Black Phosphorus: Optical Characterization, Properties and Applications

Shengxi Huang; Xi Ling

doi:10.1002/smll.201700823

Black Phosphorus: Optical Characterization, Properties and Applications

Small. 2017 Oct;13(38). doi: 10.1002/smll.201700823. Epub 2017 Jul 28.

Authors

Shengxi Huang^{1

2}, Xi Ling³

Affiliations

¹ Department of Electrical Engineering, The Pennsylvania State University, University Park, PA, 16802, USA.
² Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, MA, 02139, USA.
³ Department of Chemistry, Division of Materials Science and Engineering, Boston University, Boston, MA, 02215, USA.

PMID: 28752956
DOI: 10.1002/smll.201700823

Abstract

The rise of black phosphorus (BP) as a new family member of two-dimensional (2D) materials brings new concepts and applications to the field, because of the infrared band gap and anisotropic properties of such materials. Among many excellent properties of BP, the optical property attracts special attention in recent years. Optical methods have been widely and successfully used in characterizing BP, not only to obtain the structural information (such as thickness and crystalline orientation), but also to probe the fundamental properties of BP in terms of the behavior of electrons, phonons, excitons etc. In this Review, a comprehensive understanding about the optical characterization of BP such as Raman, absorption, and photoluminescence is presented. Also, the unique optical properties and applications explored in recent years are reviewed.

Keywords: 2D materials; black phosphorus; optical properties.

Publication types

Review
Research Support, U.S. Gov't, Non-P.H.S.
Research Support, Non-U.S. Gov't