A Simple Optoelectronic Tongue Discriminates Amino Acids

Abstract

A self-assembled nine-element optoelectronic tongue consisting of a positively charged water-soluble poly(para-phenyleneethynylene) and three metal ions (Fe²⁺ , Co²⁺ , and Cu²⁺ ) at three different pH values (7, 10, and 13) discriminates all of the 20 natural amino acids in water. Unknown identification was not ideal. Addition of a highly positively charged green fluorescent protein in the presence of Fe²⁺ , Co²⁺ , and Cu²⁺ increased the unknown identification to above 86 %. Linear discriminant analysis (LDA) orders the responses according to the amino acid type, that is, hydrophobic, polar, anionic, or cationic.

Keywords: amino acids; linear discriminant analysis; optoelectronic tongue; poly(para-phenyleneethynylene)s; sensors.