Sorption-luminescence method for determination of terbium using Transcarpathian clinoptilolite

V O Vasylechko; G V Gryshchouk; V P Zakordonskiy; L O Vasylechko; M Schmidt; I M Leshchack; Ya M Kalychak; S R Bagday

doi:10.1016/j.talanta.2017.06.052

Sorption-luminescence method for determination of terbium using Transcarpathian clinoptilolite

Talanta. 2017 Nov 1:174:486-492. doi: 10.1016/j.talanta.2017.06.052. Epub 2017 Jun 21.

Authors

V O Vasylechko¹, G V Gryshchouk², V P Zakordonskiy², L O Vasylechko³, M Schmidt⁴, I M Leshchack², Ya M Kalychak², S R Bagday²

Affiliations

¹ Faculty of Chemistry, Ivan Franko National University of Lviv, 6 Kyryla and Mefodiya Str., 79005 Lviv, Ukraine; Department of Science and Environmental Protection, Lviv University of Trade and Economics, 9 Samchuka Str., 79011 Lviv, Ukraine.
² Faculty of Chemistry, Ivan Franko National University of Lviv, 6 Kyryla and Mefodiya Str., 79005 Lviv, Ukraine.
³ Lviv Polytechnic National University, 12 Bandera Str., 79013 Lviv, Ukraine.
⁴ Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, 01187 Dresden, Germany.

PMID: 28738612
DOI: 10.1016/j.talanta.2017.06.052

Abstract

Sorption-luminescent method for terbium determination based on natural Transcarpathian clinoptilolite without using of complex synthetic organic compounds and toxic solvents was proposed. Optimal luminophore preparation conditions are sorption of Tb(III) on zeolite in the borate buffer solution with pH 8.25 and further calcination of clinoptilolite-Tb(III) samples at 500°C. For luminescence excitation the rays with wavelength of λ = 220nm of were used. Luminescence intensity at λ = 545nm was selected as analytical parameter for a quantitative terbium determination. Definable range of Tb(III) concentration with the detection limit of 1ngmL^-1 is within of 3-1140ngmL^-1. The proposed method can be used for the terbium determination in the presence of many rare earths. Sorption-luminescent method can be applied for determination of trace terbium ions in synthetic water solutions and in intermetallics. The proposed analytical method gave recoveries from 90% to 108% and R.S.D. from 0.78% to 6.2% determination of terbium.

Keywords: Clinoptilolite; Sorption-luminescence determination; Terbium.