Synthesis and characterization of a new nano lead(II) 0-D coordination supramolecular compound: A precursor to produce pure phase nano-sized lead(II) oxide

Mohammad Jaafar Soltanian Fard; Payam Hayati; Hakimeh Sadat Naraghi; Sayed Abbas Tabeie

doi:10.1016/j.ultsonch.2017.04.023

Synthesis and characterization of a new nano lead(II) 0-D coordination supramolecular compound: A precursor to produce pure phase nano-sized lead(II) oxide

Ultrason Sonochem. 2017 Nov:39:129-136. doi: 10.1016/j.ultsonch.2017.04.023. Epub 2017 Apr 18.

Authors

Mohammad Jaafar Soltanian Fard¹, Payam Hayati², Hakimeh Sadat Naraghi³, Sayed Abbas Tabeie³

Affiliations

¹ Department of Chemistry, Faculty of Chemical Science, Firoozabad Branch, Islamic Azad University, P.O. Box 74715-117, Firoozabad, Fars, Iran. Electronic address: mohammadjaafar_soltanian@yahoo.com.
² Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra 08193, Barcelona, Spain; Department of Chemistry, Dashtestan Branch, Islamic Azad University, Borazjan, Iran. Electronic address: payam.hayati@icn2.cat.
³ Department of Chemistry, Faculty of Chemical Science, Firoozabad Branch, Islamic Azad University, P.O. Box 74715-117, Firoozabad, Fars, Iran.

PMID: 28732929
DOI: 10.1016/j.ultsonch.2017.04.023

Abstract

Nano-structure of a new 0D Pb(II) coordination supramolecular compound, [Pb₄(8-Quin)₆](ClO₄)₂(1), L=8-HQuin=8-hydroxyquinolin ligand has been synthesized by use of a sonochemical process and characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRPD), Fourier transform infrared spectroscopy (FTIR) and elemental analyses. The structure of compound 1 was determined by single-crystal X-ray diffraction. The single crystal X-ray data of compound 1 implies that the Pb⁺² ions are five coordinated. Each lead atom is coordinated to nitrogen and oxygen atoms of 8-hydroxyquinolin ligand. Topological analysis shows that the compound 1 is 1,2,3,4,4M12-1net. Nanoparticles of lead(II) oxide have been prepared by calcination of lead(II) coordination polymer at 500°C that were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRPD) and IR spectroscopy.

Keywords: Coordination supramolecular; Lead(II) oxide; Nanoparticles; Ultrasonic.