Self-assembled Co-BaZrO3 nanocomposite thin films with ultra-fine vertically aligned Co nanopillars

Jijie Huang; Leigang Li; Ping Lu; Zhimin Qi; Xing Sun; Xinghang Zhang; Haiyan Wang

doi:10.1039/c7nr01122a

Self-assembled Co-BaZrO₃ nanocomposite thin films with ultra-fine vertically aligned Co nanopillars

Nanoscale. 2017 Jun 14;9(23):7970-7976. doi: 10.1039/c7nr01122a.

Authors

Jijie Huang¹, Leigang Li, Ping Lu, Zhimin Qi, Xing Sun, Xinghang Zhang, Haiyan Wang

Affiliation

¹ School of Materials Engineering, Purdue University, West Lafayette, IN 47907, USA. hwang00@purdue.edu.

PMID: 28574068
DOI: 10.1039/c7nr01122a

Abstract

A simple one-step pulsed laser deposition (PLD) method has been applied to grow self-assembled metal-oxide nanocomposite thin films. The as-deposited Co-BaZrO₃ films show high epitaxial quality with ultra-fine vertically aligned Co nanopillars (diameter <5 nm) embedded in a BZO matrix. The diameter of the nanopillars can be further tuned by varying the deposition frequency. The metal and oxide phases grow separately without inter-diffusion or mixing. Taking advantage of this unique structure, a high saturation magnetization of ∼1375 emu cm^-3 in the Co-BaZrO₃ nanocomposites has been achieved and further confirmed by Lorentz microscopy imaging in TEM. Furthermore, the coercivity values of this nanocomposite thin films range from 600 Oe (20 Hz) to 1020 Oe (2 Hz), which makes the nanocomposite an ideal candidate for high-density perpendicular recording media.