Bioinspired Structural Colors Fabricated with ZnO Quasi-Ordered Nanostructures

ACS Appl Mater Interfaces. 2017 Jun 7;9(22):19057-19062. doi: 10.1021/acsami.6b15892. Epub 2017 May 30.

Abstract

Despite their advantages in different applications, structural colors are difficult to use because of the inability to change a structural color once it is implemented, as well as their high fabrication costs; implementing multiple structural colors simultaneously on one substrate is a challenge as well. In this study, structural colors were reproduced using quasi-ordered scattering to mitigate these issues. To this end, a ZnO flower-like structure having unimodal distributions of size and spacing was fabricated by ZnO hydrothermal growth. This fabricated nanostructure has a thickness on the order of 103 nm and a diameter on the order of 102 nm. The thickness and diameter increase in proportion with the synthesis time (thickness growth rate = 43 nm/min, diameter growth rate = 20 nm/min). The shape of the nanostructure can be easily tuned by simply adjusting the synthesis and etching times. This method combines the advantages of top-down and bottom-up synthetic approaches in that the structural color can be continuously modified once fabricated.

Keywords: MEMS (microelectromechanical systems); ZnO; hydrothermal growth; nanostructure; structural color.