Citrus maxima (Pomelo) juice mediated eco-friendly synthesis of ZnO nanoparticles: Applications to photocatalytic, electrochemical sensor and antibacterial activities

Spectrochim Acta A Mol Biomol Spectrosc. 2017 Oct 5:185:11-19. doi: 10.1016/j.saa.2017.05.032. Epub 2017 May 16.

Abstract

In the present work, Zinc oxide nanoparticles (ZnO Nps) have been successfully prepared through a simple, effective and low cost solution combustion method using Zn (NO3)2·6H2O as an oxidizer, chakkota (Common name=Pomelo) fruit juice as novel fuel. X-ray diffraction pattern indicates the hexagonal wurtzite structure with average crystallite size of ~22nm. ZnO Nps were characterized with the aid of different spectroscopic techniques such as Raman spectroscopy, Fourier Transform Infrared spectroscopy, Photoluminescence and UV-Visible spectroscopy. FTIR shows characteristic ZnO vibrational mode at 393cm-1. SEM images show that the particles are agglomerated. TEM image shows the size of the particles are about 10-20nm. Further, in order to establish practical applicability of the synthesized ZnO Nps, photocatalytic degradation of methylene blue (MB) dye as a model system was studied in presence of UV (665nm) light. In addition to this, the antibacterial activity was screen against 3 bacterial strains and electrochemical sensor performance towards the quantification of dopamine at nano molar concentrations was also explored.

Keywords: Antibacterial; Chakkota (Pomelo); Dye degradation; Sensor; ZnO Nps.

MeSH terms

  • Anti-Bacterial Agents / chemistry
  • Anti-Bacterial Agents / metabolism
  • Anti-Bacterial Agents / pharmacology*
  • Bacteria / drug effects
  • Biodegradation, Environmental / drug effects*
  • Citrus / chemistry*
  • Electrochemical Techniques
  • Green Chemistry Technology / methods*
  • Hydrogen-Ion Concentration
  • Kinetics
  • Metal Nanoparticles / chemistry*
  • Microbial Sensitivity Tests
  • Photolysis / drug effects
  • X-Ray Diffraction
  • Zinc Oxide / chemistry*
  • Zinc Oxide / metabolism
  • Zinc Oxide / pharmacology

Substances

  • Anti-Bacterial Agents
  • Zinc Oxide