Synthesis of high surface area mesoporous MnO2 via a "metastable" aqueous interfacial reaction

Xingpu Wang; Shuhui Huo; Rongfang Wang; Hui Wang; Dan J L Brett; Shan Ji

doi:10.1016/j.jcis.2017.05.005

Synthesis of high surface area mesoporous MnO₂ via a "metastable" aqueous interfacial reaction

J Colloid Interface Sci. 2017 Oct 1:503:76-85. doi: 10.1016/j.jcis.2017.05.005. Epub 2017 May 4.

Authors

Xingpu Wang¹, Shuhui Huo¹, Rongfang Wang², Hui Wang³, Dan J L Brett⁴, Shan Ji⁵

Affiliations

¹ College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.
² Institute of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China. Electronic address: wrf38745779@126.com.
³ Institute of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China.
⁴ Electrochemical Innovation Lab, Department of Chemical Engineering, and Chemistry Dept. University College London, London WC1E 7JE, UK.
⁵ Electrochemical Innovation Lab, Department of Chemical Engineering, and Chemistry Dept. University College London, London WC1E 7JE, UK. Electronic address: shan.ji@ucl.ac.uk.

PMID: 28500942
DOI: 10.1016/j.jcis.2017.05.005

Abstract

In this work, a metastable aqueous interface was fabricated for synthesizing mesoporous and high surface area MnO₂. When urea was used as the additive, hierarchical spheres self-organized from ultrathin nano-sheets were obtained. Its porous structure could be controlled through adjusting the urea concentration, and a maximum surface area of 407m² g^-1 was achieved by this method, which is larger than the reported values. Due to the porous structure and high surface area, as-prepared MnO₂ exhibited a specific capacitance of 775.4 F g^-1 at a current density of 0.1 A g^-1, and exhibited a 63.5% capacitance retention when the current density was increased from 0.1 A g^-1 to 5A g^-1. Durability studies showed a 63.7% capacitance retention after 2500 cycles. The metastable interfacial reaction approach could also be extended to other alloys with large surface area and porous structure, such as CoB alloy. This method provides a simple and low-cost method to synthesize high surface area and mesoporous materials.

Keywords: Electrochemical capacitors; Hierarchical structure; Interfacial reaction; Manganese dioxide; Porous.