Hydrogen production from organic/inorganic hydrides is a promising strategy for the development of novel clean energy resources to replace fossil fuels and satisfy ever-increasing energy demands. Most current processes involve small flammable chemicals and are catalyzed by noble metals in basic media with the release of the greenhouse gas CO2 . Herein, we describe an alternative pathway for highly efficient and robust H2 production through a dehydrogenation reaction between water and N,N-dimethylformamide catalyzed by Cu/Cu2 O catalysts formed in situ. The catalysts exhibit high and robust activity for H2 production. Importantly, the formation of H2 as the sole gas and the valuable by-product N,N-dimethylaminoformic acid make this process clean and valuable with 100 % atom economy.
Keywords: catalytic stability; copper/copper(I) oxide; dehydrogenation; heterogeneous catalysis; hydrogen production.
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