Alkyne-Substituted N-Heterophenes

Sebastian Hahn; Silke Koser; Manuel Hodecker; Olena Tverskoy; Frank Rominger; Andreas Dreuw; Uwe H F Bunz

doi:10.1002/chem.201701304

Alkyne-Substituted N-Heterophenes

Chemistry. 2017 Jun 16;23(34):8148-8151. doi: 10.1002/chem.201701304. Epub 2017 May 22.

Authors

Sebastian Hahn¹, Silke Koser¹, Manuel Hodecker², Olena Tverskoy¹, Frank Rominger¹, Andreas Dreuw², Uwe H F Bunz¹

Affiliations

¹ Organisch Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
² Interdisziplinares Zentrum für Wissenschaftliches Rechnen (IWR), Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 205, 69120, Heidelberg, Germany.

PMID: 28452183
DOI: 10.1002/chem.201701304

Abstract

The synthesis and characterization of novel S-shaped N-heterophenes is reported. The targets contain a central anthracene connected to two heterophenanthrene units. N-Heterophenes are synthesized by reacting Boldt's 1,2,6,7-anthracenetetraone with different dialkynylated ortho-diaminobenzenes. The condensation yields range from 63 to 75 %; all of the N-heterophenes are stable and isolable.

Keywords: arene; condensation; heterocycle; organic light-emitting diode..