Observation of the 162Dy-164Dy Isotope Shift for the 0 → 16 717.79 cm-1 Optical Transition

Appl Spectrosc. 2017 Aug;71(8):1938-1946. doi: 10.1177/0003702817702661. Epub 2017 Apr 27.

Abstract

In this work, we report a newly observed isotope shift between 162Dy and 164Dy isotopes for the 0 → 16 717.79 cm-1 (598.003 nm) optical transition. We compared the newly observed results against two other lines (597.452 nm and 598.859 nm), which we measured in this work, and were already reported in the literature. The newly observed 162-164 Dy isotope shift, shows at least a 20% larger isotope shift than the isotope shifts for the other two lines investigated. The larger 162-164 isotope shift observed for the 598.003 nm line could lead to an increased isotope selectivity for atomic vapor laser isotope separation (AVLIS). Hence, this line could be a good choice for application in AVLIS. Experimental data available in the literature for the 597.452 nm and 598.859 nm lines, enabled us to perform simulations of spectra for both lines, in order to confirm the accuracy of our experimental measurements.

Keywords: Isotope shifts; atomic spectroscopy; dysprosium; dysprosium isotope shifts; high-resolution laser spectroscopy; laser spectroscopy.