The influence of P/As substitution in the melilite-like Na2Co(P2-xAsx)O7 (x = 0.40 and 0.93) solid solutions

Chokri Issaoui; Hammouda Chebbi; Abderrahmen Guesmi

doi:10.1107/S2053229617003771

The influence of P/As substitution in the melilite-like Na₂Co(P_2-xAs_x)O₇ (x = 0.40 and 0.93) solid solutions

Acta Crystallogr C Struct Chem. 2017 Apr 1;73(Pt 4):331-336. doi: 10.1107/S2053229617003771. Epub 2017 Mar 21.

Authors

Chokri Issaoui¹, Hammouda Chebbi¹, Abderrahmen Guesmi¹

Affiliation

¹ Université de Tunis El Manar, Faculté des Sciences, Laboratoire de Matériaux, Cristallochimie et Thermodynamique Appliquée, El Manar II, 2092 Tunis, Tunisia.

PMID: 28378717
DOI: 10.1107/S2053229617003771

Abstract

To investigate the influence of P/As substitution on structures and electrical properties, e.g. the effect on material densities, two new solid P/As-doped solutions, Na₂CoP_1.60As_0.40O₇ (disodium cobalt diphosphorus arsenic heptaoxide) and Na₂CoP_1.07As_0.93O₇ (disodium cobalt phosphorus arsenic heptaoxide), with melilite-like structures have been synthesized by solid-state reactions. Their unit-cell parameters are in agreement with Vegard's law. The obtained structural models were investigated by the bond valence sum (BVS) and charge distribution (CHARDI) validation tools and, for the latter, the structures are described as being built on anion-centred polyhedra. The frameworks can be described as layered and formed by {[Co(P,As)₂O₇]^2-}_∞ slabs, with alkali cations sandwiched between the layers and with the interlayer spaces increased due to P/As substitution. The BVS model was extended to a preliminary simulation of the sodium conduction properties in the studied structural type and suggests that the most probable sodium conduction pathways are bidimensional, at the (002) planes.

Keywords: Na2Co(P,As)2O7; P/As substitution; bidimensional conduction pathways; bond valence sum (BVS); charge distribution (CHARDI); crystal structure; sodium; sodium conduction properties; solid solutions.