Micellization in vegetable oils: A structural characterisation

Colloids Surf B Biointerfaces. 2017 Jun 1:154:279-286. doi: 10.1016/j.colsurfb.2017.03.025. Epub 2017 Mar 21.

Abstract

The solubilisation of polar and polyphenol antioxidant in vegetable oils was studied. It was shown that the use of a polyglyceryl-3-diisostearate (PG3DS), a bio-sourced emulsifier well known in cosmetics, increases the yield of solubilisation thanks to some aggregation properties analysed using x-ray scattering technique. We show indeed that PG3DS forms reverse aggregates with a critical concentration that depends on the oil polarity. PG3DS reverse aggregates are elongated with a polar core and cannot be really swollen by addition of water. This supramolecular organisation allows however an efficient solubilisation of polar antioxidants in vegetable oils.

Keywords: Polyphenol antioxidant; Reverse micelle; SAXS; Vegetable oil.

MeSH terms

  • Antioxidants / chemistry*
  • Benzhydryl Compounds / chemistry
  • Cosmetics / chemistry*
  • Emulsifying Agents
  • Flavones / chemistry
  • Glucosides / chemistry
  • Glycerol / analogs & derivatives*
  • Humans
  • Iridoid Glucosides
  • Iridoids / chemistry
  • Micelles
  • Phenylethyl Alcohol / analogs & derivatives
  • Phenylethyl Alcohol / chemistry
  • Plant Oils / chemistry*
  • Solubility
  • Stearic Acids / chemistry*
  • Waxes / chemistry*

Substances

  • Antioxidants
  • Benzhydryl Compounds
  • Cosmetics
  • Emulsifying Agents
  • Flavones
  • Glucosides
  • Iridoid Glucosides
  • Iridoids
  • Micelles
  • Plant Oils
  • Stearic Acids
  • Waxes
  • luteolin 5-O-glucopyranoside
  • 3,4-dihydroxyphenylethanol
  • oleuropein
  • jojoba wax
  • Phenylethyl Alcohol
  • Glycerol
  • galvinoxyl