Pseudocapacitive performance of a solution-processed β-Co(OH)2 electrode monitored through its surface morphology and area

P S Gaikar; S T Navale; S L Gaikwad; Ahmed Al-Osta; V V Jadhav; P R Arjunwadkar; Mu Naushad; Rajaram S Mane

doi:10.1039/c6dt04581b

Pseudocapacitive performance of a solution-processed β-Co(OH)₂ electrode monitored through its surface morphology and area

Dalton Trans. 2017 Mar 7;46(10):3393-3399. doi: 10.1039/c6dt04581b.

Authors

P S Gaikar¹, S T Navale², S L Gaikwad³, Ahmed Al-Osta³, V V Jadhav³, P R Arjunwadkar¹, Mu Naushad⁴, Rajaram S Mane⁵

Affiliations

¹ Department of Physics, Institute of Science, Nagpur, 440008, MS, India.
² Nanshan District Key Lab for Biopolymers and Safety Evaluation, College of Materials Science and Engineering, Shenzhen University, Shenzhen, Guangdong, PR China.
³ Centre for Nanomaterials & Energy Devices, School of Physical Sciences, SRTM University, 431606, Nanded, India.
⁴ Department of Chemistry, College of Science, King Saud University, Bld#5, Riyadh, Saudi Arabia. rajarammane70@srtmun.ac.in.
⁵ Centre for Nanomaterials & Energy Devices, School of Physical Sciences, SRTM University, 431606, Nanded, India and Department of Chemistry, College of Science, King Saud University, Bld#5, Riyadh, Saudi Arabia. rajarammane70@srtmun.ac.in.

PMID: 28239712
DOI: 10.1039/c6dt04581b

Abstract

In the present study, beta-cobalt hydroxide (β-Co(OH)₂) electrodes of various nanostructures and surface areas, viz. nano-rhombuses (NRs), nano-plates (NPs), and nano-grass (NGs), have been synthesized directly onto a stainless-steel (SS) substrate using a simple, economical and binder-free chemical solution-process, utilizing three cobalt precursor salts, i.e. cobalt acetate, cobalt chloride, and cobalt nitrate, respectively. Structural elucidation proves the crystallite size, type and phase-purity of β-Co(OH)₂, whereas the surface morphology analysis supports the evolution of the above mentioned nanostructures of various surface areas. The electrochemical pseudocapacitor performance investigation demonstrates a specific capacitance (S_c) of 367 F g^-1 at 1 mA cm^-2 for the NP-type morphology, which is higher than that that displayed by the other morphologies. This change in S_c value is attributed to different charge transfer resistance values, which have been obtained from electrochemical impedance spectroscopy spectra. Finally, we attempt to correlate the relationship between the surface morphology, i.e. surface area, and the charge transfer resistance with the obtained specific capacitance value of the respective electrode.