Crystal structure of poly[tetra-μ2-cyanido-1:2κ8N: C-bis-(dimethyl sulfoxide-1κ O)diargentate(I)iron(II)]

Olesia I Kucheriv; Dina D Naumova; Inna I Tokmenko; Ruslan A Polunin; Kateryna V Terebilenko

doi:10.1107/S2056989017001049

Crystal structure of poly[tetra-μ₂-cyanido-1:2κ⁸N: C-bis-(dimethyl sulfoxide-1κ O)diargentate(I)iron(II)]

Acta Crystallogr E Crystallogr Commun. 2017 Jan 27;73(Pt 2):270-272. doi: 10.1107/S2056989017001049. eCollection 2017 Feb 1.

Authors

Olesia I Kucheriv¹, Dina D Naumova¹, Inna I Tokmenko², Ruslan A Polunin³, Kateryna V Terebilenko¹

Affiliations

¹ Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, Ukraine.
² National O.O. Bogomoletz Medical University, 13 T. Shevchenko Blvd., Kyiv, Ukraine.
³ Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, Ukraine; L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky 31, Kyiv 01601, Ukraine.

Abstract

In the title polymeric complex, [Fe{OS(CH₃)₂}₂{Ag(CN)₂}₂], the Fe^II cation is located at an inversion centre and is coordinated by four cyanide (CN^-) anions and two dimethyl sulfoxide mol-ecules in a slightly compressed N₄O₂ octa-hedral geometry, the Ag^I cation is C-coordinated by two CN^- anions in a nearly linear geometry. The CN^- anions bridge the Fe^II and Ag^I cations to form a two-dimensional polymeric structure extending parallel to (102). In the crystal, the nearest Ag⋯Ag distance between polymeric sheets is 3.8122 (12) Å. The crystal studied was a twin with a contribution of 0.2108 (12) for the minor component.

Keywords: FeII complex; Hofmann clathrate analogue; crystal structure; dicyanidoargentate; metal–organic framework.