High-Throughput Continuous Hydrothermal Synthesis of Transparent Conducting Aluminum and Gallium Co-doped Zinc Oxides

ACS Comb Sci. 2017 Apr 10;19(4):239-245. doi: 10.1021/acscombsci.6b00118. Epub 2017 Mar 8.

Abstract

High-throughput continuous hydrothermal flow synthesis was used to generate a library of aluminum and gallium-codoped zinc oxide nanoparticles of specific atomic ratios. Resistivities of the materials were determined by Hall Effect measurements on heat-treated pressed discs and the results collated into a conductivity-composition map. Optimal resistivities of ∼9 × 10-3 Ω cm were reproducibly achieved for several samples, for example, codoped ZnO with 2 at% Ga and 1 at% Al. The optimum sample on balance of performance and cost was deemed to be ZnO codoped with 3 at% Al and 1 at% Ga.

Keywords: conducting; continuous; doped zinc oxides; high-throughput; hydrothermal.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aluminum / chemistry*
  • Electric Conductivity
  • Gallium / chemistry*
  • Light
  • Nanoparticles / chemistry*
  • Particle Size
  • Surface Properties
  • Zinc Oxide / chemistry*

Substances

  • Gallium
  • Aluminum
  • Zinc Oxide