Fluorescent Supramolecular Polymeric Materials

Abstract

Fluorescent supramolecular polymeric materials are rising stars in the field of fluorescent materials not only because of the inherent optoelectronic properties originating from their chromophores, but also due to the fascinating stimuli-responsiveness and reversibility coming from their noncovalent connections. Especially, these noncovalent connections influence the fluorescence properties of the chromophores because their state of aggregation and energy transfer can be regulated by the assembly-disassembly process. Considering these unique properties, fluorescent supramolecular polymeric materials have facilitated the evolution of new materials useful for applications in fluorescent sensors, probes, as imaging agents in biological systems, light-emitting diodes, and organic electronic devices. In this Review, fluorescent supramolecular polymeric materials are classified depending on the types of main driving forces for supramolecular polymerization, including multiple hydrogen bonding, electrostatic interactions, π-π stacking interactions, metal-coordination, van der Waals interactions and host-guest interactions. Through the summary of the studies about fluorescent supramolecular polymeric materials, the status quo of this research field is assessed. Based on existing challenges, directions for the future development of this field are furnished.

Keywords: fluorescence; host−guest systems; pillararenes; responsiveness; supramolecular polymers.