Disordered Cellulose-Based Nanostructures for Enhanced Light Scattering

ACS Appl Mater Interfaces. 2017 Mar 8;9(9):7885-7890. doi: 10.1021/acsami.6b15986. Epub 2017 Feb 22.

Abstract

Cellulose is the most abundant biopolymer on Earth. Cellulose fibers, such as the one extracted form cotton or woodpulp, have been used by humankind for hundreds of years to make textiles and paper. Here we show how, by engineering light-matter interaction, we can optimize light scattering using exclusively cellulose nanocrystals. The produced material is sustainable, biocompatible, and when compared to ordinary microfiber-based paper, it shows enhanced scattering strength (×4), yielding a transport mean free path as low as 3.5 μm in the visible light range. The experimental results are in a good agreement with the theoretical predictions obtained with a diffusive model for light propagation.

Keywords: cellulose nanocystals; diffusion; disorder; photonic glass; photonics; scattering.