The effect of adding position for tannery sludge in a co-processing cement rotary kiln on the chromium leachability of the cement produced was assessed in laboratory scale. Cement clinkers and pastes were produced and evaluated based on analysis of the cement quality, characterization of the clinker crystalline phases, and extraction toxicity of heavy metals in the resulting cements (using the toxicity characteristic leaching procedure (TCLP) and the Chinese GB/T 30810-2014 standard). It was found that the amount of sludge added (up to 0.7% of the feed composition) and use of different addition points for the sludge had no detrimental effect on the resulting cement quality. The retention ratios of heavy metals during sintering were related to their volatilities and the sludge addition points. The Cr concentration in leachate generated by the TCLP was far below the regulatory limit (5mg/L); however, when using the GB/T 30810-2014 procedure, the Cr concentration in the leachate exceeded the regulatory limit (200μg/L) when the sludge addition was greater than or equal to 0.5% and it was added at the kiln main burner position. Based on our laboratory study, tannery sludge might be added at the decomposing furnace addition point to reduce the Cr leachability of the resulting cement.
Keywords: Cement; Chromium; Leaching; Tannery sludge; Temperature.
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