Nucleophilic displacement reactions of 5'-derivatised nucleosides in a vibration ball mill

Beilstein J Org Chem. 2017 Jan 13:13:87-92. doi: 10.3762/bjoc.13.11. eCollection 2017.

Abstract

Vibration ball-milling in a zirconia-lined vessel afforded clean and quantitative nucleophilic displacement reactions between 4-methoxybenzylthiolate salts and nucleoside 5'-halides or 5'-tosylates in five to 60 minutes. Under these conditions, commonly-encountered nucleoside cyclisation byproducts (especially of purine nucleosides) were not observed. Liquid-assisted grinding of the same 5'-iodide and 5'-tosylate substrates with potassium selenocyanate in the presence of DMF produced the corresponding 5'-selenocyanates in variable yields over the course of between one and eleven hours thereby avoiding the preparation and use of hygroscopic tetrabutylammonium salts.

Keywords: ball mill; chalcogen; mechanochemistry; nucleophilic substitution; nucleoside.