Light-driven reversible surface functionalization with anthracenes: visible light writing and mild UV erasing

Chem Commun (Camb). 2017 Feb 4;53(10):1599-1602. doi: 10.1039/c6cc09897e. Epub 2017 Jan 20.

Abstract

We introduce a methodology to reversibly pattern planar surfaces via the light-induced dimerization of anthracenes, particularly involving a 9-triazolylanthracene motif. Specifically, we demonstrate that the visible light-induced forward reaction can be employed to pattern small molecule species as well as polymers in a spatially resolved fashion. Under UV irradiation, the generated patterns can be erased to regenerate reactive areas, which are then available for a new functionalization step. The dynamic change in surface chemistry is evidenced by ToF-SIMS.