Easy, fast and environmental friendly method for the simultaneous extraction of the 16 EPA PAHs using magnetic molecular imprinted polymers (mag-MIPs)

J Chromatogr B Analyt Technol Biomed Life Sci. 2017 Feb 15:1044-1045:63-69. doi: 10.1016/j.jchromb.2016.12.009. Epub 2017 Jan 3.

Abstract

An easy and environmental friendly method, based on the use of magnetic molecular imprinted polymers (mag-MIPs) is proposed for the simultaneous extraction of the 16 U.S. EPA polycyclic aromatic hydrocarbons (PAHs) priority pollutants. The mag-MIPs based extraction protocol is simple, more sensitive and low organic solvent consuming compared to official methods and also adequate for those PAHs more retained in the particulate matter. The new proposed extraction method followed by HPLC determination has been validated and applied to different types of water samples: tap water, river water, lake water and mineral water.

Keywords: Extraction procedure; Magnetic molecular imprinted polymers (mag-MIPs); Polycyclic aromatic hydrocarbons (PAHs); Water quality.

MeSH terms

  • Chromatography, High Pressure Liquid
  • Green Chemistry Technology / methods*
  • Limit of Detection
  • Linear Models
  • Magnets / chemistry*
  • Molecular Imprinting / methods*
  • Polycyclic Aromatic Hydrocarbons / analysis*
  • Polycyclic Aromatic Hydrocarbons / chemistry
  • Polycyclic Aromatic Hydrocarbons / isolation & purification*
  • Reproducibility of Results
  • Water Pollutants, Chemical / analysis*
  • Water Pollutants, Chemical / chemistry
  • Water Pollutants, Chemical / isolation & purification*
  • Water Quality

Substances

  • Polycyclic Aromatic Hydrocarbons
  • Water Pollutants, Chemical