One-step fabrication of biomimetic superhydrophobic surface by electrodeposition on magnesium alloy and its corrosion inhibition

J Colloid Interface Sci. 2017 Apr 1:491:313-320. doi: 10.1016/j.jcis.2016.12.022. Epub 2016 Dec 18.

Abstract

A facile, rapid and one-step electrodeposition process has been employed to construct a superhydrophobic surface with micro/nano scale structure on a Mg-Sn-Zn (TZ51) alloy, which is expected to be applied as a biodegradable biomedical implant materials. By changing the electrodeposition time, the maximum contact angle of the droplet was observed as high as 160.4°±0.7°. The characteristics of the as-prepared surface were conducted by field emission scanning electron microscopy (FE-SEM), X-ray photoelectron spectroscopy (XPS) and Fourier-transform infrared spectroscopy (FT-IR). Besides, the anti-corrosion performance of the coatings in stimulated body fluid (SBF) solution were investigated by electrochemical measurement. The results demonstrated that the anti-corrosion property of superhydrophobic surface was greatly improved. This method show beneficial effects on the wettability and corrosion behavior, and therefore provides a efficient route to mitigate the undesirable rapid corrosion of magnesium alloy in favor of application for clinical field.

Keywords: Biomedical implant materials; Corrosion resistance; Electrodeposition; Magnesium alloy; Superhydrophobic.

MeSH terms

  • Alloys / chemistry*
  • Biomimetic Materials / chemical synthesis*
  • Biomimetic Materials / chemistry
  • Corrosion
  • Electroplating*
  • Hydrophobic and Hydrophilic Interactions
  • Magnesium / chemistry*
  • Particle Size
  • Surface Properties

Substances

  • Alloys
  • Magnesium