On entropy change measurements around first order phase transitions in caloric materials

J Phys Condens Matter. 2017 Feb 22;29(7):075401. doi: 10.1088/1361-648X/aa50d1. Epub 2016 Dec 23.

Abstract

In this work we discuss the measurement protocols for indirect determination of the isothermal entropy change associated with first order phase transitions in caloric materials. The magneto-structural phase transitions giving rise to giant magnetocaloric effects in Cu-doped MnAs and FeRh are used as case studies to exemplify how badly designed protocols may affect isothermal measurements and lead to incorrect entropy change estimations. Isothermal measurement protocols which allow correct assessment of the entropy change around first order phase transitions in both direct and inverse cases are presented.