Controlled Synthesis of Atomically Layered Hexagonal Boron Nitride via Chemical Vapor Deposition

Molecules. 2016 Nov 29;21(12):1636. doi: 10.3390/molecules21121636.

Abstract

Hexagonal boron nitrite (h-BN) is an attractive material for many applications including electronics as a complement to graphene, anti-oxidation coatings, light emitters, etc. However, the synthesis of high-quality h-BN is still a great challenge. In this work, via controlled chemical vapor deposition, we demonstrate the synthesis of h-BN films with a controlled thickness down to atomic layers. The quality of as-grown h-BN is confirmed by complementary characterizations including high-resolution transition electron microscopy, atomic force microscopy, Raman spectroscopy and X-ray photo-electron spectroscopy. This work will pave the way for production of large-scale and high-quality h-BN and its applications as well.

Keywords: chemical vapor deposition; hexagonal boron nitride; synthesis.

MeSH terms

  • Boron Compounds / chemical synthesis*
  • Boron Compounds / chemistry
  • Gases / chemistry
  • Graphite / chemistry
  • Hot Temperature
  • Materials Testing / methods*
  • Microscopy, Atomic Force
  • Nanostructures / chemistry*
  • Nickel / chemistry*
  • Photoelectron Spectroscopy
  • Spectrum Analysis, Raman
  • Surface Properties

Substances

  • Boron Compounds
  • Gases
  • boron nitride
  • Graphite
  • Nickel