Metal-assisted chemical etching using sputtered gold: a simple route to black silicon

Sci Technol Adv Mater. 2011 Jul 7;12(4):045001. doi: 10.1088/1468-6996/12/4/045001. eCollection 2011 Aug.

Abstract

We report an accessible and simple method of producing 'black silicon' with aspect ratios as high as 8 using common laboratory equipment. Gold was sputtered to a thickness of 8 nm using a low-vacuum sputter coater. The structures were etched into silicon substrates using an aqueous H2O2/HF solution, and the gold was then removed using aqua regia. Ultrasonication was necessary to produce columnar structures, and an etch time of 24 min gave a velvety, non-reflective surface. The surface features after 24 min etching were uniformly microstructured over an area of square centimetres.

Keywords: etching; gold; nanostructure; silicon; sputtering.