Investigating the nitrogen dioxide concentrations in the boundary layer by using multi-axis spectroscopic measurements and comparison with satellite observations

Environ Sci Pollut Res Int. 2017 Jan;24(3):2827-2839. doi: 10.1007/s11356-016-7907-3. Epub 2016 Nov 12.

Abstract

This study emphasizes on near surface observation of chemically active trace gases such as nitrogen dioxide (NO2) over Islamabad on a regular basis. Absorption spectroscopy using backscattered extraterrestrial light source technique was used to retrieve NO2 differential slant column densities (dSCDs). Mini multi-axis-differential optical absorption spectroscopy (MAX-DOAS) instrument was used to perform ground-based measurements at Institute of Environmental Sciences and Engineering (IESE), National University of Sciences and Technology (NUST) Islamabad, Pakistan. Tropospheric vertical column densities (VCDs) of NO2 were derived from measured dSCDs by using geometric air mass factor approach. A case study was conducted to identify the impact of different materials (glass, tinted glass, and acrylic sheet of various thicknesses used to cover the instrument) on the retrieval of dSCDs. Acrylic sheet of thickness 5 mm was found most viable option for casing material as it exhibited negligible impact in the visible wavelength range. Tropospheric NO2 VCD derived from ground-based mini MAX-DOAS measurements exceeded two times the Pak-NEQS levels and showed a reasonable comparison (r 2 = 0.65, r = 0.81) with satellite observations (root mean square bias of 39 %) over Islamabad, Pakistan.

Keywords: Air quality; Mini MAX-DOAS; NO2; Pakistan; Spectroscopy.

MeSH terms

  • Air Pollutants / analysis*
  • Environmental Monitoring / methods
  • Nitrogen Dioxide / analysis*
  • Ozone / analysis
  • Pakistan
  • Spectrum Analysis / methods

Substances

  • Air Pollutants
  • Ozone
  • Nitrogen Dioxide