Removal of arsenic(III) from water by magnetic binary oxide particles (MBOP): Experimental studies on fixed bed column

Rajesh M Dhoble; Pratap Reddy Maddigapu; Sadhana S Rayalu; A G Bhole; Ashwinkumar S Dhoble; Shubham R Dhoble

doi:10.1016/j.jhazmat.2016.09.075

Removal of arsenic(III) from water by magnetic binary oxide particles (MBOP): Experimental studies on fixed bed column

J Hazard Mater. 2017 Jan 15;322(Pt B):469-478. doi: 10.1016/j.jhazmat.2016.09.075. Epub 2016 Oct 3.

Authors

Rajesh M Dhoble¹, Pratap Reddy Maddigapu², Sadhana S Rayalu³, A G Bhole⁴, Ashwinkumar S Dhoble⁵, Shubham R Dhoble⁶

Affiliations

¹ Civil Engineering Department, G.H. Raisoni Academy of Engineering and Technology, Nagpur, M.S., India. Electronic address: rmdhoble@rediffmail.com.
² Environmental Materials Division, National Environmental Engineering Research Institute, Nagpur (CSIR-NEERI) M.S., India. Electronic address: p_maddigapu@neeri.res.in.
³ Environmental Materials Division, National Environmental Engineering Research Institute, Nagpur (CSIR-NEERI) M.S., India. Electronic address: s_rayalu@neeri.res.in.
⁴ Department of Civil Engineering, Visvesvaraya National Institute of Technology, Nagpur, M.S., India. Electronic address: agbhole@yahoo.co.in.
⁵ Department of Mechanical Engineering, Visvesvaraya National Institute of Technology, Nagpur, M.S., India. Electronic address: asdhoble71@gmail.com.
⁶ Electronics and Instrumentation Engineering, Birla Institute of Technology, Pilani, Rajashtan, India. Electronic address: f2013445@pilani.bits-pilani.ac.in.

PMID: 27776861
DOI: 10.1016/j.jhazmat.2016.09.075

Abstract

Magnetic binary oxide particles (MBOP) were prepared by template method using chitosan in the laboratory for the removal of As(III) from water. The prepared MBOP has super paramagnetic property which is sufficient for magnetic separation. Column study was performed at two different flow rates of 2.0ml/min and 5.0ml/min and comparison was made with regenerated MBOP, commercial activated carbon and commercial activated alumina. It is observed that fresh MBOP has higher breakthrough time and capacity than regenerated MBOP by a factor of 1.25 and 1.37 respectively. In Logit method, the values of K (adsorption rate constant) and N (adsorption capacity coefficient) were obtained as 0.2066 (L/mgh) and 1014(mg/L) for 5.0ml/min flow rate. All the drinking water parameters are within the limit of BIS 10500-2012. Toxicity characteristic leaching procedure (TCLP) and semi dynamic tests were performed for the mix ratios of 01:02:01, 01:02:05 and 01:02:10 and were found safe for the disposal.

Keywords: Arsenic; Column study; Logit model; MBOP; TCLP.