Adsorption Processes of Lead Ions on the Mixture Surface of Bentonite and Bottom Sediments

Bull Environ Contam Toxicol. 2016 Dec;97(6):876-880. doi: 10.1007/s00128-016-1950-0. Epub 2016 Oct 17.

Abstract

The adsorption of contaminants plays an important role in the process of their elimination from a polluted environment. This work describes the issue of loading environment with lead Pb(II) and the resulting negative impact it has on plants and living organisms. It also focuses on bentonite as a natural adsorbent and on the adsorption process of Pb(II) ions on the mixture of bentonite and bottom sediment from the water reservoir in Kolíňany (SR). The equilibrium and kinetic experimental data were evaluated using Langmuir isotherm kinetic pseudo-first and pseudo-second-order rate equations the intraparticle and surface diffusion models. Langmuir isotherm model was successfully used to characterize the lead ions adsorption equilibrium on the mixture of bentonite and bottom sediment. The pseudo second-order model, the intraparticle and surface (film) diffusion models could be simultaneously fitted the experimental kinetic data.

Keywords: Bentonite; Bottom sediment; Environment; Lead adsorption.

MeSH terms

  • Adsorption
  • Bentonite / chemistry*
  • Diffusion
  • Geologic Sediments / chemistry*
  • Ions
  • Kinetics
  • Lead / chemistry*
  • Thermodynamics
  • Water Pollutants, Chemical / chemistry
  • Water Purification

Substances

  • Ions
  • Water Pollutants, Chemical
  • Bentonite
  • Lead