Glow discharge polymer hydrocarbon (GDP-CH) is used as the ablator material in inertial confinement fusion (ICF) capsules for the Laser Mégajoule and National Ignition Facility. Due to its fabrication process, GDP-CH chemical composition and structure differ from commercially available plastics and detailed knowledge of its properties in the warm dense matter regime is needed to achieve accurate design of ICF capsules. First-principles ab initio simulations of the GDP-CH principal Hugoniot up to 8 Mbar were performed using the quantum molecular dynamics (QMD) code abinit and showed that atomic bond dissociation has an effect on the compressibility. Results from these simulations are used to parametrize a quantum semiempirical model in order to generate a tabulated equation of state that includes dissociation. Hugoniot measurements obtained from an experiment conducted at the LULI2000 laser facility confirm QMD simulations as well as EOS modeling. We conclude by showing the EOS model influence on shock timing in a hydrodynamic simulation.