Raman Investigation of Precious Jewelry Collections Preserved in Paolo Orsi Regional Museum (Siracusa, Sicily) Using Portable Equipment

Appl Spectrosc. 2016 Sep;70(9):1420-31. doi: 10.1177/0003702816662592. Epub 2016 Aug 12.

Abstract

This work is a part of a large scientific project aimed at highlighting the potential of portable Raman equipment in characterizing jewelry materials preserved in museums, carried out in collaboration with gemologists and archeologists. In detail, we report the results of a measurement campaign performed for the study of gems and jewels preserved in the well-known Medagliere section at the Paolo Orsi Regional Museum of Siracusa (Sicily). The studied materials consist of exquisite examples of engraved loose gems and really rare examples of Hellenistic-Roman jewels, mainly coming from relevant Sicilian archaeological sites. Portable Raman measurements have been carried out using two instruments equipped with different excitation wavelengths. The obtained results have allowed for a complete characterization of the studied gemological materials, also suggesting sometimes misclassification for some valuable objects and gems.

Keywords: Gems; Medagliere; Siracusa; jewels; museum collection; portable Raman spectrometry.