Encapsulation of Perovskite Solar Cells for High Humidity Conditions

ChemSusChem. 2016 Sep 22;9(18):2597-2603. doi: 10.1002/cssc.201600868. Epub 2016 Aug 9.

Abstract

We examined different encapsulation strategies for perovskite solar cells by testing the device stability under continuous illumination, elevated temperature (85 °C) and ambient humidity of 65 %. The effects of the use of different epoxies, protective layers and the presence of desiccant were investigated. The best stability (retention of ∼80 % of initial efficiency on average after 48 h) was obtained for devices protected by a SiO2 film and encapsulated with a UV-curable epoxy including a desiccant sheet. However, the stability of ZnO-based cells encapsulated by the same method was found to be inferior to that of TiO2 -based cells. Finally, outdoor performance tests were performed for TiO2 -based cells (30-90 % ambient humidity). All the stability tests were performed following the established international summit on organic photovoltaic stability (ISOS) protocols for organic solar cell testing (ISOS-L2 and ISOS-O1).

Keywords: degradation; encapsulation; organometallic halide perovskite; solar cells; stability.

MeSH terms

  • Calcium Compounds / chemistry*
  • Capsules
  • Drug Stability
  • Electric Power Supplies*
  • Humidity*
  • Oxides / chemistry*
  • Solar Energy*
  • Titanium / chemistry*
  • Zinc Oxide / chemistry

Substances

  • Calcium Compounds
  • Capsules
  • Oxides
  • perovskite
  • titanium dioxide
  • Titanium
  • Zinc Oxide