Synthesis, characterization and evaluation of dewatering properties of chitosan-grafting DMDAAC flocculants

Int J Biol Macromol. 2016 Nov:92:761-768. doi: 10.1016/j.ijbiomac.2016.07.087. Epub 2016 Jul 25.

Abstract

Flocculation is one of the most widely applied techniques for water treatment and sludge dewatering. A fresh environmentally friendly and powerful flocculant is highly eager in the sludge dewatering area. In this work, a highly efficient cationic flocculant, chitosan-g-PDMDAAC was synthesized through grafting a monomer, dimethy ldiallyl ammonium chloride(DMDAAC), onto chitosan initiated by ceric sulfate under ultrasonic-assisted and conventional heating condition. The graft copolymer was characterized using FT-IR, XRD and SEM. Further, the dewatering performance of municipal activated sludge was evaluated by the filter cake moisture content and specific resistance in filtration. Its application as a flocculant for wastewater treatment was investigated. The prepared chitosan-g-PDMDAAC showed a highly effective flocculation capability for activated sludge compared with chitosan, polyacrylamide(PAM), cationic polyacrylamide(CPAM).

Keywords: Chitosan; Efficient flocculant; Sludge dewatering.

MeSH terms

  • Acrylic Resins / chemistry
  • Allyl Compounds / chemistry*
  • Chitosan / chemistry*
  • Filtration / methods*
  • Flocculation
  • Hot Temperature
  • Humans
  • Quaternary Ammonium Compounds / chemistry*
  • Sewage / analysis*
  • Sonication
  • Sulfuric Acids / chemistry*
  • Waste Disposal, Fluid
  • Water Purification / methods*

Substances

  • Acrylic Resins
  • Allyl Compounds
  • Quaternary Ammonium Compounds
  • Sewage
  • Sulfuric Acids
  • ceric sulfate
  • diallyldimethylammonium chloride
  • polyacrylamide
  • Chitosan