Improvement of Aluminum-Air Battery Performances by the Application of Flax Straw Extract

ChemSusChem. 2016 Aug 23;9(16):2103-11. doi: 10.1002/cssc.201600298. Epub 2016 Jul 28.

Abstract

The effect of a flax straw extract on Al corrosion inhibition in a strong alkaline solution was studied by using electrochemical measurements, weight-loss analysis, SEM, and FTIR spectroscopy. Flax straw extract added (3 vol %) to the 5 m KOH solution to act as a mixed-type Al corrosion inhibitor. The electrochemistry of Al in the presence of a flax straw extract in the alkaline solution, the effect of the extract on the Al morphology and surface films formed, and the corrosion inhibition mechanism are discussed. Finally, the Al-air battery discharge capacity recorded from a cell that used the flax straw extract in the alkaline electrolyte is substantially higher than that with only a pure alkaline electrolyte. This improved sustainability of the Al anode is attributed to Al corrosion inhibition and, consequently, to hydrogen evolution suppression.

Keywords: aluminum; batteries; electrochemistry; energy conversion; interfaces.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Air*
  • Aluminum / chemistry*
  • Benzopyrans / chemistry
  • Electric Power Supplies*
  • Electrochemistry
  • Flax / chemistry*
  • Humic Substances
  • Plant Extracts / chemistry*
  • Surface Properties

Substances

  • Benzopyrans
  • Humic Substances
  • Plant Extracts
  • Aluminum
  • fulvic acid