Graphene oxide (GO) was doped into four polymers films: Poly(methyl methacrylate) (PMMA), polystyrene (PS), polycarbonate (PC), and polyacrylonitrile (PAN). Following that, their optical limiting properties were investigated at 532 nm. In order to make GO hydrophobic, the lipophilic alkyl chains were connected to GO. The results showed that GO/PAN composite possesses better non-linear response than the other three composites at the same transmission (T ~ 59%). The reason were attributed to the thermal effect coming from high input fluence of laser, which improved the cross link density of PAN and further enhanced the interaction between the GO-ODA and PAN. Meanwhile, GO/PC and GO/PS had similar optical limiting property and GO/PMMA film gave the weakest optical limiting effect in our experiment.