Induced-charge electrokinetics, bipolar current, and concentration polarization in a microchannel-Nafion-membrane system

Phys Rev E. 2016 Jun;93(6):062614. doi: 10.1103/PhysRevE.93.062614. Epub 2016 Jun 29.

Abstract

The presence of a floating electrode array located within the depletion layer formed due to concentration polarization across a microchannel-membrane interface device may produce not only induced-charge electro-osmosis (ICEO) but also bipolar current resulting from the induced Faradaic reaction. It has been shown that there exists an optimal thickness of a thin dielectric coating that is sufficient to suppress bipolar currents but still enables ICEO vortices that stir the depletion layer, thereby affecting the system's current-voltage response. In addition, the use of alternating-current electro-osmosis by activating electrodes results in further enhancement of the fluid stirring and opens new routes for on-demand spatiotemporal control of the depletion layer length.