Platinum-catalysed intermolecular addition of carbonyl compounds to 1,6-enynes: investigation of a new reaction pathway

Kévin Fourmy; Mohamed El Louz; Sonia Mallet-Ladeira; Jean-Claude Daran; Odile Dechy-Cabaret; Maryse Gouygou

doi:10.1039/c6dt01725h

Platinum-catalysed intermolecular addition of carbonyl compounds to 1,6-enynes: investigation of a new reaction pathway

Dalton Trans. 2016 Sep 14;45(34):13294-9. doi: 10.1039/c6dt01725h. Epub 2016 Jul 1.

Authors

Kévin Fourmy¹, Mohamed El Louz, Sonia Mallet-Ladeira, Jean-Claude Daran, Odile Dechy-Cabaret, Maryse Gouygou

Affiliation

¹ CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France. odile.dechycabaret@ensiacet.fr maryse.gouygou@lcc-toulouse.fr.

PMID: 27363301
DOI: 10.1039/c6dt01725h

Abstract

A novel intermolecular addition of aldehydes to 1,6-enynes via a Pt-carbene intermediate provides the diastereoselective formation of valuable tricyclic compounds.