Inexpensive transparent nanoelectrode for crystalline silicon solar cells

Nanoscale Res Lett. 2016 Dec;11(1):312. doi: 10.1186/s11671-016-1533-3. Epub 2016 Jun 29.

Abstract

We report an easily manufacturable and inexpensive transparent conductive electrode for crystalline silicon (c-Si) solar cells. It is based on a silver nanoparticle network self-forming in the valleys between the pyramids of a textured solar cell surface, transformed into a nanowire network by sintering, and subsequently "buried" under the silicon surface by a metal-assisted chemical etching. We have successfully incorporated these steps into the conventional c-Si solar cell manufacturing process, from which we have eliminated the expensive screen printing and firing steps, typically used to make the macro-electrode of conducting silver fingers. The resulting, preliminary solar cell achieved power conversion efficiency only 14 % less than the conventionally processed c-Si control cell. We expect that a cell with an optimized processing will achieve at least efficiency of the conventional commercial cell, but at significantly reduced manufacturing cost.

Keywords: Antireflection coating; Crystalline silicon solar cells; Metal-assisted chemical etching; Metallic nanowire networks; Photovoltaics.