Remediation of Cr(VI)-Contaminated Soil Using the Acidified Hydrazine Hydrate

Bull Environ Contam Toxicol. 2016 Sep;97(3):392-4. doi: 10.1007/s00128-016-1862-z. Epub 2016 Jun 28.

Abstract

Acidified hydrazine hydrate was used to remediate Cr(VI)-contaminated soil. The content of water-soluble Cr(VI) in contaminated soil was 4977.53 mg/kg. The optimal initial pH of hydrazine hydrate solution, soil to solution ratio and molar ratio of Cr(VI) to hydrazine hydrate for remediation of Cr(VI)-contaminated soil were 5.0, 3:1 and 1:3, respectively. Over 99.50 % of water-soluble Cr(VI) in the contaminated soil was reduced at the optimal condition within 30 min. The remediated soil can keep stable within 4 months. Meanwhile the total phosphorus increased from 0.47 to 4.29 g/kg, indicating that using of acidified hydrazine hydrate is an effective method to remediate Cr(VI)-contaminated soil.

Keywords: Acidified hydrazine hydrate; Cr(VI)-contaminated soil; Soil remediation; Soil stability.

MeSH terms

  • Chromium / analysis*
  • Chromium / chemistry*
  • Environmental Restoration and Remediation / methods*
  • Hydrazines / chemistry*
  • Phosphorus / analysis
  • Soil / chemistry*
  • Soil Pollutants / chemistry*

Substances

  • Hydrazines
  • Soil
  • Soil Pollutants
  • Chromium
  • chromium hexavalent ion
  • hydrazine
  • Phosphorus