Synthesis of a highly active oxidation catalyst with improved distribution of titanium coordination states

Lizhi Wu; Xiujuan Deng; Shufang Zhao; Hanmei Yin; Zuoxi Zhuo; Xiangqing Fang; Yueming Liu; Mingyuan He

doi:10.1039/c6cc03318k

Synthesis of a highly active oxidation catalyst with improved distribution of titanium coordination states

Chem Commun (Camb). 2016 Jul 5;52(56):8679-82. doi: 10.1039/c6cc03318k.

Authors

Lizhi Wu¹, Xiujuan Deng¹, Shufang Zhao¹, Hanmei Yin¹, Zuoxi Zhuo¹, Xiangqing Fang², Yueming Liu¹, Mingyuan He¹

Affiliations

¹ Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, China. ymliu@chem.ecnu.edu.cn.
² Xi'an Aeronautical University, Xi'an, China.

PMID: 27333536
DOI: 10.1039/c6cc03318k

Abstract

A facile strategy is proposed to construct a highly active oxidation catalyst with optimally distributed titanium coordination states containing "TiO4" and "TiO6" species. The "TiO6" species in TS-1(+) shows a superior catalytic oxidation activity, which is 2-3 times that of "TiO4" species in TS-1.