Highly stable, luminescent core-shell type methylammonium-octylammonium lead bromide layered perovskite nanoparticles

Chem Commun (Camb). 2016 Jun 4;52(44):7118-21. doi: 10.1039/c6cc01056c. Epub 2016 May 11.

Abstract

A new protocol for the synthesis of a highly stable (over 2 months under ambient conditions) solution-processed core-shell type structure of mixed methylammonium-octylammonium lead bromide perovskite nanoparticles (5-12 nm), having spherical shape, color tunability in the blue to green spectral region (438-521 nm) and a high photoluminescence quantum yield (PLQY) of up to 92% is described. The color tunability, high PLQY and stability are due to the quantum confinement imparted by the crystal engineering associated with core-shell nanoparticle formation during growth.