Oxidative nucleophilic aromatic amination of nitrobenzenes

V V Khutorianskyi; M Sonawane; M Pošta; B Klepetářová; P Beier

doi:10.1039/c6cc02235a

Oxidative nucleophilic aromatic amination of nitrobenzenes

Chem Commun (Camb). 2016 Jun 7;52(45):7237-40. doi: 10.1039/c6cc02235a. Epub 2016 May 6.

Authors

V V Khutorianskyi¹, M Sonawane, M Pošta, B Klepetářová, P Beier

Affiliation

¹ Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nám. 2, 166 10 Prague, Czech Republic. beier@uochb.cas.cz.

PMID: 27152372
DOI: 10.1039/c6cc02235a

Abstract

Nitrobenzenes substituted with electron-acceptor groups such as halogen, nitro, trifluoromethyl, pentafluorosulfanyl, or cyano underwent oxidative nucleophilic substitution with lithium salts of arylamines to afford N-aryl-2-nitroanilines.