Very broadband diffusion-ordered NMR spectroscopy: (19)F DOSY

Chem Commun (Camb). 2016 May 25;52(42):6892-4. doi: 10.1039/c6cc02917e. Epub 2016 May 3.

Abstract

A new pulse sequence, CHORUS Oneshot, allows measurements of diffusion-ordered spectroscopy (DOSY) spectra over the full chemical shift range of (19)F for the first time. Swept-frequency pulses are used to give very broadband excitation; the sequence is a prototype for a large family of very broadband liquid state NMR methods.

MeSH terms

  • Diffusion
  • Magnetic Resonance Spectroscopy / methods*
  • Organic Chemicals / chemistry
  • Water / chemistry

Substances

  • Organic Chemicals
  • Water