Comparison of iron-bearing minerals in ordinary chondrites from H, L and LL groups using Mössbauer spectroscopy with a high velocity resolution

Spectrochim Acta A Mol Biomol Spectrosc. 2017 Feb 5:172:65-76. doi: 10.1016/j.saa.2016.04.032. Epub 2016 Apr 12.

Abstract

Ordinary chondrites from H, L and LL groups were studied using Mössbauer spectroscopy with a high velocity resolution. Mössbauer parameters of spectral components were obtained using new fitting model excluding the effect of previous misfits of troilite component. Obtained parameters were related to corresponding iron-bearing minerals in ordinary chondrites. The differences of these minerals content as well as small differences in the hyperfine parameters of the same iron-bearing minerals were revealed for different meteorites. The temperatures of equilibrium cations distribution in silicates were estimated and suitable parameters for classification of H, L and LL chondrites were supposed using Mössbauer parameters.

Keywords: (57)Fe Mössbauer spectroscopy; Hyperfine interactions; Microcrystals of iron-bearing minerals; Ordinary chondrites.