Observation of Quantum Interferences via Light-Induced Conical Intersections in Diatomic Molecules

Phys Rev Lett. 2016 Apr 8;116(14):143004. doi: 10.1103/PhysRevLett.116.143004. Epub 2016 Apr 7.

Abstract

We observe energy-dependent angle-resolved diffraction patterns in protons from strong-field dissociation of the molecular hydrogen ion H_{2}^{+}. The interference is a characteristic of dissociation around a laser-induced conical intersection (LICI), which is a point of contact between two surfaces in the dressed two-dimensional Born-Oppenheimer potential energy landscape of a diatomic molecule in a strong laser field. The interference magnitude and angular period depend strongly on the energy difference between the initial state and the LICI, consistent with coherent diffraction around a cone-shaped potential barrier whose width and thickness depend on the relative energy of the initial state and the cone apex. These findings are supported by numerical solutions of the time-dependent Schrödinger equation for similar experimental conditions.

Publication types

  • Research Support, Non-U.S. Gov't