Data on synthesis and characterization of new diglycerol based environmentally friendly non-isocyanate poly(hydroxyurethanes)

Mariusz Tryznowski; Aleksandra Świderska; Zuzanna Żołek-Tryznowska; Tomasz Gołofit; Paweł G Parzuchowski

doi:10.1016/j.dib.2015.11.034

Data on synthesis and characterization of new diglycerol based environmentally friendly non-isocyanate poly(hydroxyurethanes)

Data Brief. 2015 Nov 22:6:77-82. doi: 10.1016/j.dib.2015.11.034. eCollection 2016 Mar.

Authors

Mariusz Tryznowski¹, Aleksandra Świderska¹, Zuzanna Żołek-Tryznowska², Tomasz Gołofit¹, Paweł G Parzuchowski¹

Affiliations

¹ Warsaw University of Technology, Faculty of Chemistry, Poland.
² Warsaw University of Technology, Faculty of Production Engineering, Poland.

Abstract

This article contains original experimental data, figures and methods to the preparation of non-isocyanate poly(hydroxyurethanes) by an environmentally friendly method without the use of toxic phosgene and isocyanates from bis(2,3-dihydroxypropyl)ether dicarbonate and various diamines (Tryznowski et al., Submitted for publication) [1]. Bis(2,3-dihydroxypropyl)ether dicarbonate was obtained from a one-step procedure from commercially available diglycerol. The product was characterized by (1)H NMR, (13)C NMR, and FTIR spectroscopies and for the first time by X-Ray diffraction measurements. Then, the bis(cyclic carbonate) monomer was used as a precursor for the synthesis of various NIPUs. The NIPUs were prepared in a non-solvent process. Spectral and thermal properties of the NIPUs are compered. Here we give the procedure in order to perform bis(2,3-dihydroxypropyl)ether dicarbonate with high yield and the procedure NIPU synthesis and the complete set of monomer and NIPU analysis ((1)H NMR, (13)C NMR, FTIR, X-Ray).