N-Tosyl-1,5,2,6-dithiadiazocane: a waste-free electrophilic sulfur reagent for the efficient synthesis of medium-ring S,N-heterocycles

Tomas Javorskis; Gintautas Bagdžiūnas; Edvinas Orentas

doi:10.1039/c6cc01068g

N-Tosyl-1,5,2,6-dithiadiazocane: a waste-free electrophilic sulfur reagent for the efficient synthesis of medium-ring S,N-heterocycles

Chem Commun (Camb). 2016 Mar 21;52(23):4325-8. doi: 10.1039/c6cc01068g.

Authors

Tomas Javorskis¹, Gintautas Bagdžiūnas², Edvinas Orentas¹

Affiliations

¹ Department of Organic Chemistry, Vilnius University, Naugarduko 24, 03225 Vilnius, Lithuania. edvinas.orentas@chf.vu.lt.
² Department of Polymer Chemistry and Technology, Kaunas University of Technology, Radvilėnų pl. 19, 50254 Kaunas, Lithuania.

PMID: 26924508
DOI: 10.1039/c6cc01068g

Abstract

We report on the application of an eight-membered C2-symmetric sulfenamide derivative as a new convenient and highly reactive electrophilic sulfur-nucleophilic nitrogen synthon for the concise synthesis of medium-ring S,N-heterocyclic systems.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Heterocyclic Compounds / chemical synthesis*
Sulfur / chemistry*
Tosyl Compounds / chemistry*

Substances

Heterocyclic Compounds
Tosyl Compounds
Sulfur