Crystal structure of N'-[bis-(ethyl-sulfan-yl)methyl-idene]-2-hy-droxy-4-meth-oxy-benzohydrazide

Paras Nath; Manoj K Bharty; Rahul Chaurasia; Sanyucta Kumari; Sushil K Gupta

doi:10.1107/S2056989015021271

Crystal structure of N'-[bis-(ethyl-sulfan-yl)methyl-idene]-2-hy-droxy-4-meth-oxy-benzohydrazide

Acta Crystallogr E Crystallogr Commun. 2015 Nov 21;71(Pt 12):o967-8. doi: 10.1107/S2056989015021271. eCollection 2015 Dec 1.

Authors

Paras Nath¹, Manoj K Bharty¹, Rahul Chaurasia¹, Sanyucta Kumari¹, Sushil K Gupta²

Affiliations

¹ Department of Chemistry, Banaras Hindu University, Varanasi 221 005, India.
² School of Studies in Chemistry, Jiwaji University, Gwalior 474 011, India.

Abstract

In the title compound, C13H18N2O3S2, the amide group is in the plane of the -benzoyl ring with a C-N-N-C torsion angle of 177.63 (12)°. The two di-thio-ate groups are in an anti conformation [torsion angles = 173.68 (8) and -9.98 (10)°]. An intra-molecular N-H⋯O hydrogen bond is observed. In the crystal, an O-H⋯O hydrogen bond and a weak C-H⋯O contact involving the same acceptor atom generate an S(6) ring motif and give rise to chains along [010].

Keywords: crystal structure; dithiocarbazate; ester; hydrogen bonding.