Crystal structure of 3-(9H-carbazol-9-yl)-N'-[(E)-4-chloro-benzyl-idene]propano-hydrazide

Mehmet Akkurt; Jerry P Jasinski; Shaaban K Mohamed; Talaat I El-Emary; Mustafa R Albayati

doi:10.1107/S2056989015020770

Crystal structure of 3-(9H-carbazol-9-yl)-N'-[(E)-4-chloro-benzyl-idene]propano-hydrazide

Acta Crystallogr E Crystallogr Commun. 2015 Nov 14;71(Pt 12):o937-8. doi: 10.1107/S2056989015020770. eCollection 2015 Dec 1.

Authors

Mehmet Akkurt¹, Jerry P Jasinski², Shaaban K Mohamed³, Talaat I El-Emary⁴, Mustafa R Albayati⁵

Affiliations

¹ Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey.
² Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA.
³ Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England; Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
⁴ Department of Chemistry, Faculty of Science, Assiut University, 71515 Assiut, Egypt.
⁵ Kirkuk University, College of Science, Department of Chemistry, Kirkuk, Iraq.

Abstract

In the title compound, C22H18ClN3O, the carbazole ring system is essentially planar (r.m.s deviation = 0.003 Å), and makes a dihedral angle of 9.01 (8)° with the plane of the chloro-phenyl ring. In the crystal, neighbouring mol-ecules are linked into centrosymmetric R 2 (2)(8) dimers by pairs of N-H⋯O inter-actions and into a three-dimensional network by C-H⋯π inter-actions. The dimers are arranged into layers parallel to (010).

Keywords: bio-active molecules; crystal structure; hydrogen bonding; the carbazole ring system.