ROMP Synthesis of Iron-Containing Organometallic Polymers

Ileana Dragutan; Valerian Dragutan; Petru Filip; Bogdan C Simionescu; Albert Demonceau

doi:10.3390/molecules21020198

ROMP Synthesis of Iron-Containing Organometallic Polymers

Molecules. 2016 Feb 6;21(2):198. doi: 10.3390/molecules21020198.

Authors

Ileana Dragutan¹, Valerian Dragutan², Petru Filip³, Bogdan C Simionescu⁴, Albert Demonceau⁵

Affiliations

¹ Institute of Organic Chemistry, Romanian Academy, 202B Spl. Independentei, P. O. Box 35-108, Bucharest 060023, Romania. idragutan@yahoo.com.
² Institute of Organic Chemistry, Romanian Academy, 202B Spl. Independentei, P. O. Box 35-108, Bucharest 060023, Romania. vdragutan@yahoo.com.
³ Institute of Organic Chemistry, Romanian Academy, 202B Spl. Independentei, P. O. Box 35-108, Bucharest 060023, Romania. petrufilip@gmail.com.
⁴ Petru Poni Institute of Macromolecular Chemistry, Romanian Academy, Iasi 700487, Romania. bcsimion@icmpp.ro.
⁵ Macromolecular Chemistry and Organic Catalysis, Institute of Chemistry (B6a), University of Liege, Sart Tilman, Liege 4000, Belgium. a.demonceau@ulg.ac.be.

Abstract

The paper overviews iron-containing polymers prepared by controlled "living" ring-opening metathesis polymerization (ROMP). Developments in the design and synthesis of this class of organometallic polymers are highlighted, pinpointing methodologies and newest trends in advanced applications of hybrid materials based on polymers functionalized with iron motifs.

Keywords: ROMP; ferrocene; hybrid materials; iron-containing polymers; sandwich-complexes.

Publication types

Research Support, Non-U.S. Gov't
Review

MeSH terms

Catalysis
Iron / chemistry
Iron Compounds / chemical synthesis*
Polymerization
Polymers / chemical synthesis*

Substances

Iron Compounds
Polymers
Iron